PUBLICATION
"Re-examining the stereochemistry of polycyclic suffruticosine via TDDFT calculations, ECD spectroscopy, and chemical synthesis"
Taewan Kim, Samhwan Kim, Garam Chung, Kiyoung Park*, and Sunkyu Han*
Org. Chem. Front. 2023, 10, 5123-5129.
"Identification, Characterization, and Electronic Structures of Interconvertible Cobalt–Oxygen TAML Intermediates"
Deesha D. Malik, Wooyeol Ryu, Yujeong Kim, Gurjot Singh, Jun-Hyeong Kim, Muniyandi Sankaralingam, Yong-Min Lee, Mi Sook Seo, Mahesh Sundararajan, Daniel Ocampo, Michael Roemelt*, Kiyoung Park*, Sun Hee Kim*, Mu-Hyun Baik*, Jason Shearer*, Kallol Ray*, Shunichi Fukuzumi*, and Wonwoo Nam*
J. Am. Chem. Soc. 2024, 146, 13817-13835.
"Conformational and functional changes of the native neuropeptide somatostatin occur in the presence of copper and amyloid-beta"
Jiyeon Han, Jiwon Yoon, Jeongcheol Shin, Eunju Nam, Tongrui Qian, Yulong Li, Kiyoung Park*, Seung-Hee Lee*, Mi Hee Lim*
Nat. Chem. 2022, 14, 1021-1030.
"Efficient Nicotinamide Adenine Dinucleotide Regeneration with a Rhodium–Carbene Catalyst and Isolation of a Hydride Intermediate"
Vinothkumar Ganesan, Jennifer Juhyun Kim, Jeongcheol Shin, Kiyoung Park*, and Sungho Yoon*
Inorg. Chem. 2022, 61, 5683-5690.
"Ligand-field transition-induced C-S bond formation from nickelacycles"
Jeongcheol Shin, Jiseon Lee, Jong-Min Suh, Kiyoung Park*
Chem. Sci. 2021, 12, 15908-15915. (Hot Article)
"Light-promoted C-Cl bond-forming reductive elimination of a metal-metal bonded Pd(III)-Pd(III) complex"
Jeongcheol Shin, Kuldeep Gogoi, Kiyoung Park*
Chem. Commun. 2021, 57, 7673-7676.
"Nuclear Resonance Vibrational Spectroscopic Definition of the Fe(IV)2 Intermediate Q in Methane Monooxygenase and Its Reactivity"
Ariel Benjamin Jacobs, Rahul Banerjee, Dory Ellen Deweese, Augustin Braun, Jeffrey Thomas Babicz Jr., Leland Bruce Gee, Kyle David Sutherlin, Lars Hendrik Böttger, Yoshitaka Yoda, Makina Saito, Shinji Kitao, Yasuhiro Kobayashi, Makoto Seto, Kenji Tamasaku, John D. Lipscomb*, Kiyoung Park*, and Edward I. Solomon*
J. Am. Chem. Soc. 2021, 143, 16007-16029.
"Correlation between the C-C Cross-Coupling Activity and C-to-Ni Charge Transfer Transition of High-Valent Ni Complexes"
Jeongcheol Shin, Suyeon Gwon, Samhwan Kim, Jiseon Lee, Kiyoung Park*
J. Am. Chem. Soc. 2020, 142, 4173-4183.
"CO2 hydrogenation to formic acid over heterogenized ruthenium catalysts using a fixed bed reactor with separation units"
Kwangho Park, Gunniya Hariyanandam Gunasekar, Seong-Hoon Kim, Hongjin Park, Samhwan Kim, Kiyoung Park, Kwang-Deog Jung*, Sungho Yoon*
Green Chem. 2020, 22, 1639-1649.
"Monomeric MoS42--Derived Polymeric Chains with Active Molecular Units for Efficient Hydrogen Evolution Reaction"
Bora Seo, Gwan Yeong Jung, Se Jeong Lee, Du San Baek, Young Jin Sa, Hyeong Woo Ban, Jae Sung Son, Kiyoung Park*, Sang Kyu Kwak*, Sang Hoon Joo*
ACS Catal. 2020, 10, 652-662.
"Nuclear Resonance Vibrational Spectroscopy Definition of O2 Intermediates in an Extradiol Dioxygenase: Correlation to Crystallography and Reactivity"
Kyle D. Sutherlin, Yuko Wasada-Tsutsui, Michael M. Mbughuni, Melanie S. Rogers, Kiyoung Park, Lei V. Liu, Yeonju Kwak, Martin Srnec, Lars H. Bottger, Mathieu Frenette, Yoshitaka Yoda, Yasuhiro Kobayashi, Masayuki Kurokuzu, Makina Saito, Makoto Seto, Michael Hu, Jiyong Zhao, E. Ercan Alp, John D. Lipscomb*, Edward I. Solomon*
J. Am. Chem. Soc. 2018, 140, 16495-16513.
"Molecular Rh(III) and Ir(III) Catalysts Immobilized on Bipyridine-Based Covalent Triazine Frameworks for the Hydrogenation of CO2 to Formate"
Gunniya Hariyanandam Gunasekar, Kwangho Park, Hyeonseok Jeong, Kwang-Deog Jung, Kiyoung Park, Sungho Yoon*
Catalysts 2018, 8, 295.
"Design Strategy toward Recyclable and Highly Efficient Heterogeneous Catalysts for the Hydrogenation of CO2 to Formate"
Gunniya Hariyanandam Gunasekar, Jeongcheol Shin, Kwang-Deog Jung, Kiyoung Park, Sungho Yoon*
ACS Catal. 2018, 8, 4345-4353.
"NRVS Studies of the Peroxide Shunt Intermediate in a Rieske Dioxygenase and Its Relation to the Native Fe(II) O2 Reaction"
Kyle D. Sutherlin, Brent S. Rivard, Lars H. Bottger, Lei V. Liu, Melanie S. Rogers, Martin Srnec, Kiyoung Park, Yoshitaka Yoda, Shinji Kitao, Yasuhiro Kobayashi, Makina Saito, Makoto Seto, Michael Hu, Jiyong Zhao, John D. Lipscomb*, Edward I. Solomon*
J. Am. Chem. Soc. 2018, 140, 5544-5559.
"Stereochemistry of metal tetramethylcyclam complexes directed by an unexpected anion effect"
Jeffery S. Derrick, Yujeong Kim, Hyeonwoo Tak, Kiyoung Park*, Jaeheung Cho*, Sun Hee Kim*, Mi Hee Lim*
Dalton Trans. 2017, 46, 13166-13170.
"Peroxide activation for electrophilic reactivity by the binuclear non-heme iron enzyme AurF"
Kiyoung Park, Ning Li, Yeonju Kwak, Martin Srnec, Caleb Bell, Lei Liu, Shaun Wong, Yoshitaka Yoda, Shinji Kitao, Makoto Seto, Michael Hu, Jiyong Zhao, Carsten Krebs*, J. Martin Bollinger, Jr.*, Edward I. Solomon*
J. Am. Chem. Soc. 2017, 139, 7062-7070.
"σ-Complexation as a strategy for designing copper-based light emitters"
Yeong-Eun Kim, Jin Kim, Joon Woo Park, Kiyoung Park*, Yunho Lee*
Chem. Commun. 2017, 53, 2858-2861.
"Mechanistic Insights into Tunable Metal-Mediated Hydrolysis of Amyloid-beta Peptides"
Jeffrey S. Derrick, Jiwan Lee, Shin Jung C. Lee, Yujeong Kim, Eunju Nam, Hyeonwoo Tak, Juhye Kang, Misun Lee, Sun Hee Kim*, Kiyoung Park*, Jaeheung Cho*, Mi Hee Lim*
J. Am. Chem. Soc. 2017, 139, 2234-2244.
"Resonance Raman spectroscopic study of the interaction between co(II)rrinoids and the ATP:corrinoid adenosyltransferase PduO from Lactobacillus reuteri"
Kiyoung Park*, Paola E. Mera, Jorge C. Escalante-Semerena, Thomas C. Brunold*
J. Bio. Inorg. Chem. 2016, 21, 669-681.
"Structure/function correlations over binuclear non-heme iron active sites"
Edward I Solomon*, Kiyoung Park
J. Bio. Inorg. Chem. 2016, 21, 575-588.
“Unprecedented mechanism employed by the Salmonella enterica EutT ATP:Co(I)rrinoid adenosyltransferase precludes adenosylation of incomplete Co(II)rrinoids”
Kiyoung Park, Paola E. Mera, Theodore. C. Moore, Jorge C. Escalante-Semerena, Thomas C. Brunold*
Angew. Chem. Int. Ed., 2015, 54, 7158-7161.
“Modeling nuclear resonance vibrational spectroscopic data of binuclear nonheme iron enzymes using density functional theory”
Kiyoung Park, Edward I. Solomon*
Can. J. Chem. 2014, 92, 975-978.
"Nuclear Resonance Vibrational Spectroscopic and Computational Study of High-valent Diiron Complexes Relevant to Enzyme Intermediates"
Kiyoung Park, Caleb B. Bell III, Lei V. Liu, Dong Wang, Genqiang Xue, Yeonju Kwak, Shaun D. Wong, Kenneth M. Light, Jiyong Zhao, E. Ercan Alp, Yoshitaka Yoda, Makina Saito, Yasuhiro Kobayashi, Takehiro Ohta, Makoto Seto, Larry Que, Jr.*, and Edward I. Solomon*
Proc. Natl. Acad. Sci. USA, 2013, 110, 6275-6280.
"Nuclear Resonance Vibrational Spectroscopy and DFT Study of Peroxo-bridged Biferric Complexes: Structural Insight into Peroxy Intermediates of Binuclear Non-heme Iron Enzymes"
Kiyoung Park, Tomohiro Tsugawa, Hideki Furutachi, Yeonju Kwak, Lei V. Liu, Shaun D. Wong, Yoshitaka Yoda, Yasuhiro Kobayashi, Makina Saito, Masayuki Kurokuzu, Makoto Seto, Masatatsu Suzuki*, and Edward I. Solomon*
Angew. Chem. Int. Ed. 2013, 52, 1294-1298.
"Resonance Raman and Computational Studies of B12 cofactors"
Kiyoung Park and Thomas C. Brunold*
J. Phys. Chem. B, 2013, 117, 5397-5410.
"Elucidation of the Iron(IV)–oxo Intermediate in the Non-Haem Iron Halogenase SyrB2"
S. D. Wong, M. Srnec, M. L. Matthews, L. V. Liu, Y. Kwak, K. Park, C. B. Bell, E. E. Alp, J. Zhao, Y. Yoda, S. Kitao, M. Seto, C. Krebs*, J. M. Bollinger*, E. I. Solomon*
Nature, 2013, 499, 320-323.
"Geometric and Electronic Structure of the MnIVFeIII Cofactor in Class Ic Ribonucleotide Reductase: Correlation to the Class Ia Binuclear Non-Heme Iron Enzymes"
Y. Kwak, W. Jiang, L. M. K. Dassama, K. Park, C. B. Bell, L. V. Liu, S. D. Wong, M. Saito, Y. Kobayashi, S. Kitao, M. Seto, Y. Yoda, E. E. Alp, J. Zhao, K. Crebs*, J. M. Bollinger*, E. I. Solomon*
J. Am. Chem. Soc. 2013, 135, 17573-17584.
"Spectroscopic Characterization of Active-Site Variants of the PduO-type ATP:Corrinoid Adenosyltransferase from Lactobacillus reuteri: Insights into the Mechanism of Four-Coordinate Co(II)corrinoid Formation"
Kiyoung Park, Paola E. Mera, Jorge C. Escalante-Semerena, and Thomas C. Brunold*
Inorg. Chem. 2012, 51, 4482-4494.
"Spectroscopically validated density functional theory studies of the B12 cofactors and their interactions with enzyme active sites"
Thomas C. Brunold,* Karen S. Conrad, Matthew D. Liptak, Kiyoung Park
Coord. Chem. Rev. 2009, 253, 779-794.
"Kinetic and Spectroscopic Studies of the ATP:Corrinoid Adenosyltransferase PduO from Lactobacillus reuteri: Substrate Specificity and Insights into the Mechanism of Co(II)corrinoid Reduction"
Kiyoung Park, Paola E. Mera, Jorge C. Escalante-Semerena, and Thomas C. Brunold*
Biochemistry 2008, 47, 9007-9015.
"Structural Characterization of a Human-Type Corrinoid Adenosyltransferase Confirms That Coenzyme B12 Is Synthesized through a Four-Coordinate Intermediate"
Martin St. Maurice, Paola E. Mera, Kiyoung Park, Thomas C. Brunold, Jorge C. Escalante-Semerena, and Ivan Rayment*
Biochemistry 2008, 47, 5755-5766.
